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Tobacco Science & Technology, 2012, 3, p. 52-56., ISSN.1002-0861

Determination of phthalic acid esters in cigarette filter by GC/MS

ZHANG Hongfei; LIU Nan; BIAN Zhaoyang; TANG Gangling; HU Qingyuan
China National Tobacco Quality Supervision & Test Center, Zhengzhou 450001, P.R. China

A method for simultaneously determining 17 phthalic acid esters (PAEs) in cigarette filter was established with GC/MS. The parameters such as extraction mode, extraction solvent, extraction condition, detection condition were tested, and 45 cigarette samples were detected. The results showed that: 1) ultrasonic extraction with water and ethanol mixture for 30 minutes was effective; 2) the recoveries of the 17 PAEs ranged from 87.0% to 105.8% with the relative standard deviations (RSDs) of 2.6% to 5.4%; 3) PAEs were found in 14 samples, the detectable rate was 31.11%, in which dibutyl phthalate (DBP) was found in 4 samples with the detectable rate of 8.88%; diisobutyl phthalate (DIBP) was found in 7 samples with the detectable rate of 15.56%; and di(2-ethylhexyl)phthalate (DEHP) was found in 8 samples with the detectable rate of 17.78%. This method is suitable for simultaneously determining PAEs in cigarette filter.