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11 results

  1. Beitr. Tabakforsch. Int./Contrib. Tob. Research, 2009, 23-4, p. 203-26., ISSN.0173-783X

    Investigation of tobacco pyrolysis gases and puff-by-puff resolved cigarette smoke by single photon ionisation (SPI) - Time-of-flight Mass Spectrometry (TOFMS)

    ADAM T.; MITSCHKE S.; BAKER R.R
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    The work presented deals with the application of Single Photon Ionisation - Time-of-Flight Mass Spectrometry (SPI-TOFMS) for the investigation of tobacco smoke. SPI-TOFMS is a modern analytical technique, which enables the simultaneous analysis of a...
  2. CORESTA Meeting, Smoke Science/Product Technology, Jeju, 2007, SSPT 19

    Simultaneous on-line analysis of gas phase and particulate phase of cigarette mainstream smoke

    ADAM T.; McAUGHEY J.; MITSCHKE S.; McGRATH C.; MOCKER C.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Tobacco smoke is a complex and dynamic matrix consisting of gaseous and particulate material, in which about 4800 constituents have been identified. The chemical composition and partition between phases of the smoke can change continuously and is...
  3. CORESTA Meeting, Smoke Science/Product Technology, Jeju, 2007, SSPT 20

    Sidestream smoke analysis with Single Photon Ionisation/Time-of-Flight Mass Spectrometry (SPI-TOFMS)

    MITSCHKE S.; ADAM T.; BAKER R.R.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Recently several studies dealing with online analysis of mainstream tobacco smoke utilising photo ionisation mass spectrometry (PI-MS), namely single photon ionisation (SPI) and resonance-enhanced multi photon ionisation (REMPI) time-of-flight mass...
  4. CORESTA Congress, Paris, 2006, SS 06

    Real-time on-line characterisation of selected Hoffmann analytes in inhaled and exhaled cigarette smoke (Mouthspace) by photo ionisation time-of-flight mass spectrometry

    STREIBEL T.; SKLORZ M.; MITSCHKE S.; ADAM T.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Chemical composition of cigarette smoke has been extensively researched in the past mostly using off-line methods such as GC/MS or HPLC. Often the smoke was already aged and altered by the sampling/trapping when it was analyzed. It is known that many...
  5. CORESTA Congress, Paris, 2006, SS 18

    Application of laser ionization mass spectrometry for on-line characterization of organic compounds in main- and sidestream smoke

    ADAM T.; MITSCHKE S.; STREIBEL T.; McAUGHEY J.; BAKER R.R.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Tobacco smoke is a fast changing and extremely complex mixture containing thousands of compounds. Consequently, to account for the dynamic smoke composition analytical techniques exhibiting a very high time resolution are required. The measurement...
  6. CORESTA Congress, Paris, 2006, SS 23

    On-line real-time analysis of organic compounds in mainstream tobacco smoke: An optimised coupling between a commercial smoke machine and fast photo-ionisation time-of-flight mass spectrometry

    ZIMMERMANN R.; STREIBEL T.; MÜHLBERGER F.; ADAM T.; MITSCHKE S.; BAKER R.R.; GONIN M.; FUHRER K.; ROSE N.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Since the chemical properties of tobacco smoke are changing very rapidly during the smoking process, time-resolved analysis is required to better understand the chemistry of smoking. Puff-resolved analysis of tobacco smoke can be done by conventional...
  7. CORESTA Congress, Paris, 2006, SSPOST 11

    Discrimination of three tobacco types by application of Thermal Desorption/Photo Ionisation Time-of-Flight Mass Spectrometry as well as investigation of sidestream smoke using Single Photon Ionisation/Time-of-Flight Mass Spectrometry

    MITSCHKE S.; STREIBEL T.; ADAM T.; BAKER R.R.; McAUGHEY J.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Recently, Pyrolysis Single Photon Ionisation/Time-of-Flight Mass spectrometry (Py-SPI-TOFMS) has been applied to differentiate between three major tobacco types, Burley, Virginia, and Oriental, respectively. In doing so, tobacco samples have been...
  8. CORESTA Meeting, Smoke Science/Product Technology, Stratford-upon-Avon, 2005, SSPT 43

    Puff-by-puff resolved measurements of cigarette smoke by resonance-enhanced multi-photon ionization (REMPI) and single photon ionization (SPI) - time of flight mass spectrometry (TOFMS)

    MITSCHKE S.; ADAM T.; STREIBEL T.; BAKER R.R.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    The application of soft photo-ionization mass spectrometry methods (PIMS) for cigarette mainstream smoke (MSS) analysis is demonstrated. Resonance-enhanced multi-photon ionization (REMPI) and vacuum ultra violet light single-photon ionization (SPI)...
  9. CORESTA Meeting, Smoke Science/Product Technology, Stratford-upon-Avon, 2005, SSPT 44

    Puff-by-puff resolved tobacco smoke particulates analyzed by comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GCxGC TOFMS)

    WELTHAGEN W.; MITSCHKE S.; ADAM T.; STREIBEL T.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    The potential use of GCxGC TOFMS in the analysis of puff-by-puff resolved tobacco smoke particulate matter collected on Cambridge filters is discussed. GCxGC-TOFMS is a technique suited to study complex samples consisting out of thousands of...
  10. CORESTA Meeting, Smoke Science/Product Technology, Stratford-upon-Avon, 2005, SSPT 45

    Pyrolysis single-photon ionisation time-of-flight mass spectrometry (Py-SPI-TOFMS) for the discrimination of three tobacco types

    STREIBEL T.; ADAM T.; MITSCHKE S.; FERGE T.; BAKER R.R.; ZIMMERMANN R.
    University of Augsburg, Analytical Chemistry, Institute of Physics, Augsburg, Germany
    Pyrolysis single photon ionisation/time-of-flight mass spectrometry (Py-SPI-TOFMS) has been applied to differentiate between three major tobacco types, viz Burley, Virginia, and Oriental, respectively. SPI is known as a soft ionisation technique that...