In order to reduce the harmful compounds in cigarette smoke, two types of composite porous materials are synthesized. Based on mesoporous materials, SBA-15 and MCM-41, zeolites HZSM-5 and NaY fragments are introduced into the synthetic system and assembled with mesoporous materials. These composite porous materials combine the advantages of micro- and mesoporous materials. And they exhibit higher effects on reducing the tar free radicals, TSNAs and some vapor phase compounds than activated carbon. In another way, zeolite HZSM-5 is coated into activated carbon and tailored by alkali solution, respectively. Their ability to reduce TSNAs in mainstream smoke is also obviously improved compared with activated carbon.